Vinyl contains two sp 2 hybridized carbon atoms and three hydrogen atoms.
Alkyl aryl vinyl.
The most basic aryl group is phenyl which is made up of a benzene ring with one hydrogen atom substituted for some substituent and has the molecular formula c 6 h 5.
The key difference between these two structural components is the number of carbon and hydrogen atoms.
Enamides and enol ethers are valuable building blocks in synthetic chemistry yet their stereoselective synthesis can be challenging.
The allylic carbon atom is more reactive than normal.
Allyl groups have three carbon atoms and five hydrogen atoms.
Note that phenyl groups are not the same as benzyl groups which consists of a phenyl group attached to a methyl group and has the molecular formula c 6 h 5 ch 2.
Allyl indicates a functional group with structural formula h 2 c ch ch 2 r where r is the rest of the molecule it consists of methylene bridge ch 2 in between the vinyl group ch ch 2 and the rest of the molecule therefore allyl group contains sp 2 hybridized vinyl carbon atoms and sp 3 hybridized allyl carbon atom.
Both groups own a double bond between two carbon atoms where all the other atoms are bonded through single bonds.
A vinyl halide is clearly a species with a formula h 2c c x h in which a halide is directly bound to an olefinic bond formally this is ethylene h 2c ch 2 with one of the hydrogens substituted by a heteroatom vinyl chloride h 2c chcl is an example.
The vinyl compounds are every reactive and they polymerize to form the vinyl polymers as in the case of polyvinyl acetate polyvinyl chloride and polyvinyl fluoride.
Herein we report a new stereoselective synthesis of vinyl aryl alkynyl alkyl and thio substituted z enamides and enol ethers based on the use of vinylbenziodoxolone vbx 2019 chemical science hot article collection.